Thermal Expansion

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Discussion

Solids

ΔL  =  L0 α ΔT   linear
ΔA  =  A0 ΔT   superficial (areal)
ΔL  =  L0 ΔT   volumetric

Liquids

ΔV = V0βΔT

Liquids have higher expansivities than solids

β â‰ˆ 10−3/K, 3α â‰ˆ 10−5/K

Gases

[check out the gas laws]

behavior of gases is more complicated, gases will expand as much as pressure will allow

Coefficients of Thermal Expansion for Selected Materials
material linear
α (10−6 K−1)
  material volume
β (10−6 K−1)
aluminium 23.1   alcohol, ethyl 1120
barium ferrite 10   gasoline 950
brass 20.3   jet fuel, kerosene 990
carbon, diamond 1.18   mercury 181
carbon, graphite ∥ 6.5   water, liquid (1 °C) −50
carbon, graphite ⊥ 0.5   water, liquid (4 °C) 0
chromium 4.9   water, liquid (10 °C) 88
concrete 8 ~ 12   water, liquid (20 °C) 207
copper 16.5   water, liquid (30 °C) 303
germanium 6.1   water, liquid (40 °C) 385
glass 8.5   water, liquid (50 °C) 457
gold 14.2   water, liquid (60 °C) 522
iron 11.8   water, liquid (70 °C) 582
lead 28.9   water, liquid (80 °C) 640
nickel 13.3   water, liquid (90 °C) 695
platinum 8.8      
plutonium 54      
silicon 4.68      
silver 18.9      
solder, lead-tin 25      
steel, stainless 17.3      
steel, structural 12      
tin 22      
titanium 8.5      
tungsten 4.5      
uranium 13.9      
water, ice (0 °C) 51      
zinc 30.2      

water


Thermal Expansion of Water [magnify]

Thermal Expansion of Water [magnify]

plutonium

Plutonium undergoes more phase transitions at ordinary pressures than any other element. As plutonium is heated it transforms through six different crystal structures before melting -- α [alpha], β [beta], γ [gamma], δ [delta], δ′ [delta prime], and ε [epsilon]. Physical properties like density and thermal expansion vary significantly from phase to phase making it one of the more difficult metals to machine and work. The metallurgy of plutonium is best left to the experts.

One of plutonium's unique physical properties is that the pure metal exhibits six solid-state phase transformations before reaching its liquid state, passing from alpha, beta, gamma, delta, delta-prime, to epsilon. Large volume expansions and contractions occur between the stable room-temperature alpha phase and the element's liquid state. Another unusual feature is that unalloyed plutonium melts at a relatively low temperature, approximately 640 °C, to yield a liquid of higher density than the solid from which it melts. In addition, the elastic properties of the delta face-centered cubic (fcc) phase of plutonium are highly directional (anisotropic). That is, the elasticity of the metal varies widely along different crystallographic directions by as much as a factor of six to seven. [LLNL]


Thermal Expansion of Plutonium [magnify]

Summary

Problems

practice

  1. Write something.
    • Answer it.
  2. Write something else.
    • Answer it.
  3. Write something different.
    • Answer it.
  4. Write something completely different.
    • Answer it.

numerical

  1. A steel bridge is built in several segments, each 20 m long. The gap between segments is 4 cm at 18 °C. What is the maximum temperature that the bridge can manage before buckling?
  2. Due to the high specific heat and low conductivity of water, only the uppermost 10% of the oceans is able to undergo any significant temperature change.
    1. The natural variation in ocean levels is about 10 cm from September to March. By how much does the mean temperature of the upper ocean change during this time?
    2. Global warming is likely to cause a rise in sea level for a number of reasons, one of which is the thermal expansion of water. Determine the rise in sea level for every 1.0 C° temperature increase in the upper ocean.
     
    Data for the Oceans
    surface area 3.61 × 1014 m2
    mean depth 3794 m
    mean temperature, overall 3.5 °C
    mean temperature, top 10% 10 °C
     
  3. How much taller is the Eiffel Tower on the hottest day of the summer (25 °C) than the coldest day of the winter (2 °C)? The tower is 324 m tall measured from the top of the flagpole. Assume the tower is built of structural steel. (It's actually made of "puddle iron".)

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